Immobilization and release of copper species from a microstructured polypyrrole matrix

Copper species immobilization in hollow rectangular-sectioned microtubes of polypyrrole (PPy) electrosynthesized on 316L stainless steel was carried out using two different methods. One of them involved the immobilization after the PPy electropolymerization and the other one during the electrosynthe...

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Bibliographic Details
Authors: González, Belén, Brugnoni, Lorena Inés, Flamini, Daniel Omar, Quinzani, Lidia Maria, Saidman, Silvana Beatriz
Format: article
Status:Published version
Publication Date:2017
Country:Argentina
Institution:Consejo Nacional de Investigaciones Científicas y Técnicas
Repository:CONICET Digital (CONICET)
Language:English
OAI Identifier:oai:ri.conicet.gov.ar:11336/64663
Online Access:http://hdl.handle.net/11336/64663
Access Level:Open access
Keyword:Antibacterial Activity
Copper
Electropolymerization
Polypyrrole
Salicylate
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
Description
Summary:Copper species immobilization in hollow rectangular-sectioned microtubes of polypyrrole (PPy) electrosynthesized on 316L stainless steel was carried out using two different methods. One of them involved the immobilization after the PPy electropolymerization and the other one during the electrosynthesis process. The electrodes modified with copper species were rotated at different speeds in well water under open-circuit potential conditions. The release of copper species from the PPy matrix and the antibacterial activity against Escherichia coli were analyzed. The obtained results demonstrate that the amount of copper species released as well as the bactericidal effects against E. coli increases with rotation speed. The PPy coating modified with copper species after the electropolymerization reaction exhibited the best performance in terms of antibacterial activity and corrosion protection. These electrodes were tested in a lab-scale continuous flow system for well water disinfection.