A novel chemometric strategy for the estimation of extra virgin olive oil adulteration with edible oils

A useful procedure for the qualitative and quantitative determination of vegetable oils (canola, hazelnut, pomace and high linoleic/oleic sunflower) as adulterants in commercial samples of extra virgin olive oil, has been developed. Partial least squares (PLS) was employed for the analysis of Fourie...

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Detalhes bibliográficos
Autores: Maggio, Ruben Mariano, Cerretani, Lorenzo, Chiavaro, Emma, Kaufman, Teodoro Saul, Bendini, Alessandra
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2010
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/133261
Acesso em linha:http://hdl.handle.net/11336/133261
Access Level:acceso abierto
Palavra-chave:ADULTERATION
FTIR
PARTIAL LEAST SQUARES MODEL
VIRGIN OLIVE OIL
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descrição
Resumo:A useful procedure for the qualitative and quantitative determination of vegetable oils (canola, hazelnut, pomace and high linoleic/oleic sunflower) as adulterants in commercial samples of extra virgin olive oil, has been developed. Partial least squares (PLS) was employed for the analysis of Fourier transform infrared spectroscopy (FTIR) spectral data of the blend oil samples. Calibration models were constructed for extra virgin olive oil purity, with wavelength selection in the infrared region, according to their predictive ability, with first derivative and mean centering used as data pretreatment. PLS models were internally validated by the leave-one-out procedure. The method developed was very suitable for the determination of modeled adulterants but it may also reveal an adulteration even if it does not derive from the adulterants employed in this study.