Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate

The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C4H9)4N]2[Fe(CN)5NO]·2H2O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR)...

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Detalles Bibliográficos
Autores: Chacón Villalba, Elizabeth, Guida, Jorge Alberto, Piro, Oscar Enrique, Castellano, E. E., Aymonino, Pedro Jose
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2001
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/98620
Acceso en línea:http://hdl.handle.net/11336/98620
Access Level:acceso abierto
Palabra clave:CRYSTAL STRUCTURE
METASTABLE STATES
TETRABUTYLAMMONIUM NITROPRUSSIDE
VIBRATIONAL SPECTRA
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
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repository_id_str
spelling Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrateChacón Villalba, ElizabethGuida, Jorge AlbertoPiro, Oscar EnriqueCastellano, E. E.Aymonino, Pedro JoseCRYSTAL STRUCTUREMETASTABLE STATESTETRABUTYLAMMONIUM NITROPRUSSIDEVIBRATIONAL SPECTRAhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C4H9)4N]2[Fe(CN)5NO]·2H2O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3221, D63, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.Fil: Chacón Villalba, Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Piro, Oscar Enrique. Universidad Nacional de la Plata. Facultad de Cs.exactas. Instituto de Física de la Plata; ArgentinaFil: Castellano, E. E.. Universidade de Sao Paulo; BrasilFil: Aymonino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaSpringer/Plenum Publishers2001-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98620Chacón Villalba, Elizabeth; Guida, Jorge Alberto; Piro, Oscar Enrique; Castellano, E. E.; Aymonino, Pedro Jose; Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate; Springer/Plenum Publishers; Journal Of Chemical Crystallography; 31; 3; 10-2001; 155-1661074-1542CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1023/A:1014367821364info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1023/A:1014367821364info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T13:42:42Zoai:ri.conicet.gov.ar:11336/98620instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 13:42:42.525CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
spellingShingle Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
Chacón Villalba, Elizabeth
CRYSTAL STRUCTURE
METASTABLE STATES
TETRABUTYLAMMONIUM NITROPRUSSIDE
VIBRATIONAL SPECTRA
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
title_short Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_full Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_fullStr Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_full_unstemmed Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
title_sort Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate
dc.creator.none.fl_str_mv Chacón Villalba, Elizabeth
Guida, Jorge Alberto
Piro, Oscar Enrique
Castellano, E. E.
Aymonino, Pedro Jose
author Chacón Villalba, Elizabeth
author_facet Chacón Villalba, Elizabeth
Guida, Jorge Alberto
Piro, Oscar Enrique
Castellano, E. E.
Aymonino, Pedro Jose
author_role author
author2 Guida, Jorge Alberto
Piro, Oscar Enrique
Castellano, E. E.
Aymonino, Pedro Jose
author2_role author
author
author
author
dc.subject.none.fl_str_mv CRYSTAL STRUCTURE
METASTABLE STATES
TETRABUTYLAMMONIUM NITROPRUSSIDE
VIBRATIONAL SPECTRA
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
topic CRYSTAL STRUCTURE
METASTABLE STATES
TETRABUTYLAMMONIUM NITROPRUSSIDE
VIBRATIONAL SPECTRA
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description The crystal structure of tetrabutylammonium nitroprusside dihydrate (TBANPDH, [(C4H9)4N]2[Fe(CN)5NO]·2H2O) was determined by single crystal X-ray diffraction (XRD) and the compound was also studied, as well as the anhydrous salt (TBANP), by room and low temperature Fourier Transform Infra-Red (FTIR) and room temperature Fourier Transform Near Infra-Red Raman (FTNIRR) spectroscopies. In addition to the ground states (GS), the metastable excited states (MSI and MSII) generated by laser excitation (488 nm) at low temperature were IR studied, both of the dihydrate and the anhydrate. TBANPDH crystallizes in the trigonal space group P3221, D63, with a = b = 13.777(2), c = 22.039(2) Å, and Z = 3. The structure was solved employing 1273 independent XR reflections, with I > 2σ(I), by Patterson and Fourier methods and refined by full-matrix least-squares to R1 = 0.054.
publishDate 2001
dc.date.none.fl_str_mv 2001-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/98620
Chacón Villalba, Elizabeth; Guida, Jorge Alberto; Piro, Oscar Enrique; Castellano, E. E.; Aymonino, Pedro Jose; Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate; Springer/Plenum Publishers; Journal Of Chemical Crystallography; 31; 3; 10-2001; 155-166
1074-1542
CONICET Digital
CONICET
url http://hdl.handle.net/11336/98620
identifier_str_mv Chacón Villalba, Elizabeth; Guida, Jorge Alberto; Piro, Oscar Enrique; Castellano, E. E.; Aymonino, Pedro Jose; Crystal structure of tetrabutylammonium nitroprusside dihydrate, [(C4H9)4N]2[Fe(CN)5NO]·2H2O, and vibrational spectra of ground and metastable excited states of the dihydrate and the anhydrate; Springer/Plenum Publishers; Journal Of Chemical Crystallography; 31; 3; 10-2001; 155-166
1074-1542
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1023/A:1014367821364
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1023/A:1014367821364
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer/Plenum Publishers
publisher.none.fl_str_mv Springer/Plenum Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 15.812429

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