Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis

This research studied chemical and thermal treatments of rosehip husk (RH), from invasive species in Patagonia Rosa rubiginosa, which is considered a main waste in the seed-oil extraction industry, to obtain added-value products by optimizing an eco-friendly pectin extraction, followed by pyrolysis...

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Detalhes bibliográficos
Autores: Torres Sciancalepore, Rodrigo Agustin, Riveros Gomez, Mathias Adrián, Zalazar García, Daniela Inés Yanina, Asensio, Daniela Anabel, Fabani, Maria Paula, Rodriguez, Rosa Ana, Fouga, Gastón Galo, Mazza, German Delfor
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/225607
Acesso em linha:http://hdl.handle.net/11336/225607
Access Level:acceso abierto
Palavra-chave:BIOMASS TO HYDROGEN
BIOMASS WASTE RECOVERY
INVASIVE SHRUB SPECIES VALORIZATION
PECTIN EXTRACTION OPTIMIZATION
ROSEHIP HUSK WASTE
SLOW-PYROLYSIS PRODUCTS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
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oai_identifier_str oai:ri.conicet.gov.ar:11336/225607
network_acronym_str AR
network_name_str Argentina
repository_id_str
dc.title.none.fl_str_mv Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
title Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
spellingShingle Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
Torres Sciancalepore, Rodrigo Agustin
BIOMASS TO HYDROGEN
BIOMASS WASTE RECOVERY
INVASIVE SHRUB SPECIES VALORIZATION
PECTIN EXTRACTION OPTIMIZATION
ROSEHIP HUSK WASTE
SLOW-PYROLYSIS PRODUCTS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
title_full Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
title_fullStr Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
title_full_unstemmed Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
title_sort Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis
dc.creator.none.fl_str_mv Torres Sciancalepore, Rodrigo Agustin
Riveros Gomez, Mathias Adrián
Zalazar García, Daniela Inés Yanina
Asensio, Daniela Anabel
Fabani, Maria Paula
Rodriguez, Rosa Ana
Fouga, Gastón Galo
Mazza, German Delfor
author Torres Sciancalepore, Rodrigo Agustin
author_facet Torres Sciancalepore, Rodrigo Agustin
Riveros Gomez, Mathias Adrián
Zalazar García, Daniela Inés Yanina
Asensio, Daniela Anabel
Fabani, Maria Paula
Rodriguez, Rosa Ana
Fouga, Gastón Galo
Mazza, German Delfor
author_role author
author2 Riveros Gomez, Mathias Adrián
Zalazar García, Daniela Inés Yanina
Asensio, Daniela Anabel
Fabani, Maria Paula
Rodriguez, Rosa Ana
Fouga, Gastón Galo
Mazza, German Delfor
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BIOMASS TO HYDROGEN
BIOMASS WASTE RECOVERY
INVASIVE SHRUB SPECIES VALORIZATION
PECTIN EXTRACTION OPTIMIZATION
ROSEHIP HUSK WASTE
SLOW-PYROLYSIS PRODUCTS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic BIOMASS TO HYDROGEN
BIOMASS WASTE RECOVERY
INVASIVE SHRUB SPECIES VALORIZATION
PECTIN EXTRACTION OPTIMIZATION
ROSEHIP HUSK WASTE
SLOW-PYROLYSIS PRODUCTS
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description This research studied chemical and thermal treatments of rosehip husk (RH), from invasive species in Patagonia Rosa rubiginosa, which is considered a main waste in the seed-oil extraction industry, to obtain added-value products by optimizing an eco-friendly pectin extraction, followed by pyrolysis of the remaining solid (RHW). The aim was to valorize the rosehip husk of an invasive species by finding the optimal conditions for pectin extraction (maximum yield and minimum CO2 emissions) and assessing the pyrolysis process together with the products obtained, finding the temperature of maximum production of each species in the gaseous product. By applying multi-objective optimization, it was found that the optimal yield was 17.83 % with 456.7 g of CO2 emitted for kg of pectin at temperature T = 79.6 ºC, time t = 30 min, and pH = 2.3. By TGA, 6 processes were identified in the pyrolysis of RHW: moisture evaporation and 5 consecutive reactions which were related to lignocellulosic biomass components decomposition. The kinetic parameters of each reaction were obtained by isoconversional method (activation energy), compensation effect method (pre-exponential factor), and master-plots method (conversion function). The pyrolysis gaseous products of energetic interest identified were CH4, H2, and C2H4, with maximum production at 630, 700, 850 ºC respectively. The main compounds found by GC-MS were diacetone alcohol, mesityl oxide, butylated hydroxytoluene, among others. The ash was analyzed by XRD and showed a high Ca concentration (46.9 %) with presence of Ca(OH)2, MgO, KCaPO4, and K4Ca(PO4)2.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/225607
Torres Sciancalepore, Rodrigo Agustin; Riveros Gomez, Mathias Adrián; Zalazar García, Daniela Inés Yanina; Asensio, Daniela Anabel; Fabani, Maria Paula; et al.; Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis; Elsevier; Journal of Environmental Chemical Engineering; 11; 5; 10-2023; 1-13
2213-3437
CONICET Digital
CONICET
url http://hdl.handle.net/11336/225607
identifier_str_mv Torres Sciancalepore, Rodrigo Agustin; Riveros Gomez, Mathias Adrián; Zalazar García, Daniela Inés Yanina; Asensio, Daniela Anabel; Fabani, Maria Paula; et al.; Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis; Elsevier; Journal of Environmental Chemical Engineering; 11; 5; 10-2023; 1-13
2213-3437
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343723015415
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2023.110802
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799196365233848320
spelling Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysisTorres Sciancalepore, Rodrigo AgustinRiveros Gomez, Mathias AdriánZalazar García, Daniela Inés YaninaAsensio, Daniela AnabelFabani, Maria PaulaRodriguez, Rosa AnaFouga, Gastón GaloMazza, German DelforBIOMASS TO HYDROGENBIOMASS WASTE RECOVERYINVASIVE SHRUB SPECIES VALORIZATIONPECTIN EXTRACTION OPTIMIZATIONROSEHIP HUSK WASTESLOW-PYROLYSIS PRODUCTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This research studied chemical and thermal treatments of rosehip husk (RH), from invasive species in Patagonia Rosa rubiginosa, which is considered a main waste in the seed-oil extraction industry, to obtain added-value products by optimizing an eco-friendly pectin extraction, followed by pyrolysis of the remaining solid (RHW). The aim was to valorize the rosehip husk of an invasive species by finding the optimal conditions for pectin extraction (maximum yield and minimum CO2 emissions) and assessing the pyrolysis process together with the products obtained, finding the temperature of maximum production of each species in the gaseous product. By applying multi-objective optimization, it was found that the optimal yield was 17.83 % with 456.7 g of CO2 emitted for kg of pectin at temperature T = 79.6 ºC, time t = 30 min, and pH = 2.3. By TGA, 6 processes were identified in the pyrolysis of RHW: moisture evaporation and 5 consecutive reactions which were related to lignocellulosic biomass components decomposition. The kinetic parameters of each reaction were obtained by isoconversional method (activation energy), compensation effect method (pre-exponential factor), and master-plots method (conversion function). The pyrolysis gaseous products of energetic interest identified were CH4, H2, and C2H4, with maximum production at 630, 700, 850 ºC respectively. The main compounds found by GC-MS were diacetone alcohol, mesityl oxide, butylated hydroxytoluene, among others. The ash was analyzed by XRD and showed a high Ca concentration (46.9 %) with presence of Ca(OH)2, MgO, KCaPO4, and K4Ca(PO4)2.Fil: Torres Sciancalepore, Rodrigo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Grupo Vinculado Instituto de Ingeniería Química | Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Grupo Vinculado Instituto de Ingeniería Química; ArgentinaFil: Riveros Gomez, Mathias Adrián. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaFil: Zalazar García, Daniela Inés Yanina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaFil: Asensio, Daniela Anabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Fabani, Maria Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; Argentina. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; ArgentinaFil: Rodriguez, Rosa Ana. Universidad Nacional de San Juan. Facultad de Ingeniería. Instituto de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas; ArgentinaFil: Fouga, Gastón Galo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comision Nacional de Energia Atomica. Gerencia Complejo Tecnologico Pilcaniyeu. Departamento de Fisicoquimica y Control de Calidad;Fil: Mazza, German Delfor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Grupo Vinculado Instituto de Ingeniería Química | Universidad Nacional del Comahue. Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas. Grupo Vinculado Instituto de Ingeniería Química; ArgentinaElsevier2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/225607Torres Sciancalepore, Rodrigo Agustin; Riveros Gomez, Mathias Adrián; Zalazar García, Daniela Inés Yanina; Asensio, Daniela Anabel; Fabani, Maria Paula; et al.; Two-step valorization of invasive species Rosa rubiginosa L. husk waste through eco-friendly optimized pectin extraction and subsequent pyrolysis; Elsevier; Journal of Environmental Chemical Engineering; 11; 5; 10-2023; 1-132213-3437CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2213343723015415info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jece.2023.110802info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:24:50Zoai:ri.conicet.gov.ar:11336/225607instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:24:50.878CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
score 15.812429

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