Scanning tunneling microscopy of electrochemically activated platinum surfaces : A direct ex-situ determination of the electrode nanotopography
A direct scanning tunneling microscopy ex-situ determination on the nanometer scale of the topography of electrochemically highly activated platinum electrodes is presented. A correlation between catalytic activity and surface microtopography becomes evident. This result gives support to a structura...
| Autores: | , , , , , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1987 |
| País: | Argentina |
| Institución: | Universidad Nacional de La Plata |
| Repositorio: | SEDICI (UNLP) |
| Idioma: | inglés |
| OAI Identifier: | oai:sedici.unlp.edu.ar:10915/126531 |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/126531 |
| Access Level: | acceso abierto |
| Palabra clave: | Ciencias Exactas Química scanning tunneling microscopy platinum electrodes electrocatalytic processes |
| Sumario: | A direct scanning tunneling microscopy ex-situ determination on the nanometer scale of the topography of electrochemically highly activated platinum electrodes is presented. A correlation between catalytic activity and surface microtopography becomes evident. This result gives support to a structural model for the activated electrode surface. In the model, a volume with a pebble-like structure allows electrocatalytic processes to occur practically free of diffusion relaxation contributions under usual voltammetric conditions. |
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