Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications

Fumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living)...

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Detalles Bibliográficos
Autores: Oberti, Tamara Gisela, Cortizo, María Susana
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:Argentina
Institución:Universidad Nacional de La Plata
Repositorio:SEDICI (UNLP)
Idioma:inglés
OAI Identifier:oai:sedici.unlp.edu.ar:10915/163969
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/163969
Access Level:acceso abierto
Palabra clave:Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
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spelling Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applicationsOberti, Tamara GiselaCortizo, María SusanaCiencias ExactasQuímicapolyfumarateradical polymerizationthermal propertiestissue engineeringenergy applicationsFumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living) are detailed and their characteristic kinetic parameters are shown. For example, the use of the initiator 2,2′-azobis(isobutyrate) (MAIB) allows to obtain polymers of higher molecular weight since it generates more stable primary radicals than those achieved with other azo initiators. The emergence of different controlled radical polymerization methodologies has resulted in the generation of new fumaric homo and copolymers with different properties. The structural characteristics of these materials analyzed by spectroscopic techniques and their relationship with properties in solutions, glass transition temperature, thermal stability and mechanical behavior are detailed in the present work. Finally, several biomedical and energy applications are described in which copolymers from fumaric and acrylic monomers were employed, combined or not with natural polymers to be used as scaffolds in the regeneration of bone and cartilage tissue, drug delivery systems, as flow or asphalt modifiers. From the complete reading of this review, it will be possible to achieve a global vision starting from the synthesis to the application of fumaric polymers in which the need of scaling this type of productions to reach specific industrial applications is visualized.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/163969enginfo:eu-repo/semantics/altIdentifier/issn/0014-3057info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2023.112389info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2024-05-08T13:22:02Zoai:sedici.unlp.edu.ar:10915/163969Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292024-05-08 13:22:02.406SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
spellingShingle Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
Oberti, Tamara Gisela
Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
title_short Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_full Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_fullStr Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_full_unstemmed Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
title_sort Homo- and copolymers based on dialkyl fumarates: A review on radical polymerization, properties, current and future applications
dc.creator.none.fl_str_mv Oberti, Tamara Gisela
Cortizo, María Susana
author Oberti, Tamara Gisela
author_facet Oberti, Tamara Gisela
Cortizo, María Susana
author_role author
author2 Cortizo, María Susana
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
topic Ciencias Exactas
Química
polyfumarate
radical polymerization
thermal properties
tissue engineering
energy applications
description Fumaric polymers are macromolecules obtained from 1,2-disubstituted monomers, which provide special structural characteristics and therefore attractive physicochemical properties for their applications. Thus, in the present review, different radical polymerization mechanisms (conventional or living) are detailed and their characteristic kinetic parameters are shown. For example, the use of the initiator 2,2′-azobis(isobutyrate) (MAIB) allows to obtain polymers of higher molecular weight since it generates more stable primary radicals than those achieved with other azo initiators. The emergence of different controlled radical polymerization methodologies has resulted in the generation of new fumaric homo and copolymers with different properties. The structural characteristics of these materials analyzed by spectroscopic techniques and their relationship with properties in solutions, glass transition temperature, thermal stability and mechanical behavior are detailed in the present work. Finally, several biomedical and energy applications are described in which copolymers from fumaric and acrylic monomers were employed, combined or not with natural polymers to be used as scaffolds in the regeneration of bone and cartilage tissue, drug delivery systems, as flow or asphalt modifiers. From the complete reading of this review, it will be possible to achieve a global vision starting from the synthesis to the application of fumaric polymers in which the need of scaling this type of productions to reach specific industrial applications is visualized.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
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info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/163969
url http://sedici.unlp.edu.ar/handle/10915/163969
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0014-3057
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.eurpolymj.2023.112389
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
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dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
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instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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