4.A BET approach to multilayer adsorption in swelling products

An equation for multimolecular sorption is presented. It is based on the BET model with the assumption that the adsorbing surface can be divided in two regions: A region that supports only a limited number of adsorbed layers due to geometric restrictions, and another region that can adsorb an unlimi...

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Detalles Bibliográficos
Autores: Pantuso, F. S., Tolaba, Marcela Patricia, Aguerre, Roberto Jorge
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/24863
Acceso en línea:http://hdl.handle.net/11336/24863
Access Level:acceso abierto
Palabra clave:Swelling
Water Adsorption
Porosity
Isotherm Shapes
Multilayer Adsorption
Free Energy of Adsorption
https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
Descripción
Sumario:An equation for multimolecular sorption is presented. It is based on the BET model with the assumption that the adsorbing surface can be divided in two regions: A region that supports only a limited number of adsorbed layers due to geometric restrictions, and another region that can adsorb an unlimited number of layers. The proposed equation is applicable to type 2 and 3 isotherms (BDDT classification), and was successfully used to fit water sorption equilibrium data of some foodstuff from literature for the water activity range 0.05?0.90, and a temperature range from 10 to 70 C.