Dependence of the Structural Stability of MCM-41 on the Impregnating Iron Solution

The MCM-41 mesoporous material was chosen as support of very small iron oxide particles. To study the preparation conditions that allow to preserve the support structure four samples were prepared. The solids were characterized by atomic absorption spectroscopy (AAS), specific surface area (BET), X-...

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Detalhes bibliográficos
Autores: Cagnoli, Maria Virginia, Alvarez, Ana María, Bengoa, Jose Fernando, Gallegos, Norma Graciela, Mogni, Liliana Verónica, Gonzalez Oddera, Mariela, Marchetti, Sergio Gustavo, Mercader, Roberto Carlos
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2003
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/62514
Acesso em linha:http://hdl.handle.net/11336/62514
Access Level:acceso abierto
Palavra-chave:Fe/Mcm-41 Preparation
MÖSsbauer Fe/Mcm-41 Characterization
Supported Iron Particles
https://purl.org/becyt/ford/2.2
https://purl.org/becyt/ford/2
Descrição
Resumo:The MCM-41 mesoporous material was chosen as support of very small iron oxide particles. To study the preparation conditions that allow to preserve the support structure four samples were prepared. The solids were characterized by atomic absorption spectroscopy (AAS), specific surface area (BET), X-ray diffraction (XRD) and Mössbauer spectroscopy at 298 and 22 K. The absence of water in the impregnation step is essential to avoid the collapse of the structure.