Electrode behaviour of nickel in HCl-dimethylsulphoxide solutions : I. The cathodic evolution of hydrogen
The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reactio...
| Autores: | , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1973 |
| País: | Argentina |
| Institución: | Universidad Nacional de La Plata |
| Repositorio: | SEDICI (UNLP) |
| Idioma: | inglés |
| OAI Identifier: | oai:sedici.unlp.edu.ar:10915/119948 |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119948 |
| Access Level: | acceso abierto |
| Palabra clave: | Ciencias Exactas Química Hydrogen Nickel HCl-dimethylsulphoxide |
| Sumario: | The electrochemical reduction of the solvated hydrogen ion dissolved in DMSO as HCl was investigated from 25 to 45°C, at different concentrations and ionic strength. Stationary and non-stationary techniques were employed to obtained the kinetic parameters. The results were interpreted with a reaction scheme involving an initial electron transfer as <i>rds</i>, probably followed by an electrochemical desorption step. |
|---|