Effect of the support on the selective hydrogenation of benzeneover ruthenium catalysts. 1. Al2O3 and SiO2
The effect of the support on the liquid phase selective hydrogenation of benzene to cyclohexene over Ru catalysts was studied. Catalysts were prepared using RuCl3 as precursor and characterized by hydrogen chemisorption, XPS and TPR. The reaction was carried out at 373 K and 2 MPa using a stirred ta...
| Autores: | , , , |
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| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2005 |
| País: | Argentina |
| Recursos: | Consejo Nacional de Investigaciones Científicas y Técnicas |
| Repositorio: | CONICET Digital (CONICET) |
| Idioma: | inglés |
| OAI Identifier: | oai:ri.conicet.gov.ar:11336/78023 |
| Acesso em linha: | http://hdl.handle.net/11336/78023 |
| Access Level: | acceso abierto |
| Palavra-chave: | Cyclohexene Effect Of the Support Ru Catalysts Selective Hydrogenation https://purl.org/becyt/ford/2.7 https://purl.org/becyt/ford/2 |
| Resumo: | The effect of the support on the liquid phase selective hydrogenation of benzene to cyclohexene over Ru catalysts was studied. Catalysts were prepared using RuCl3 as precursor and characterized by hydrogen chemisorption, XPS and TPR. The reaction was carried out at 373 K and 2 MPa using a stirred tank reactor. It was found that the catalytic activity is not influenced by the Ru dispersion. More electron-deficient Ru species are present on Al 2O3 than on SiO2. The electronic state of Ru affects the selectivity to cyclohexene. |
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