Centrifugal Distortion Constants in 1.3 Propiolactone
The centrifugal distortion constants for 0-CH₂ -CH₂ -C = 0 were calculated using Dowling and Watson’s formalisms. From the fitting analysis and the deviation of predicted transitions it is concluded that the second formalism must be adopted. For the different parameters we have: A'=12406.012 ±0...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 1974 |
| País: | Argentina |
| Institución: | Universidad Nacional de La Plata |
| Repositorio: | SEDICI (UNLP) |
| Idioma: | inglés |
| OAI Identifier: | oai:sedici.unlp.edu.ar:10915/120284 |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/120284 |
| Access Level: | acceso abierto |
| Palabra clave: | Física Centrifugal distortion |
| Sumario: | The centrifugal distortion constants for 0-CH₂ -CH₂ -C = 0 were calculated using Dowling and Watson’s formalisms. From the fitting analysis and the deviation of predicted transitions it is concluded that the second formalism must be adopted. For the different parameters we have: A'=12406.012 ±0.005 MHz; B'=5244.456 ± 0.002 MHz; C'=3869.191 ± 0.002 MHz; dj= -2.08± 0 .05 kHz; djk= -23.6 3± 0.95 kHz; dk= - 33.43 ± 1.69 kHz; dWJ= (0.56± 0.01)X l0-6; dwK = (5.08 ± 0.22)X 10 -6. |
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