Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation

Palladium-modified Co-ZnAland Cu-ZnAl materials were used and found active for the catalytic oxidation of propene and propane. According to the results obtained by XRD, TPR and XPS, the zinc aluminate-supported phases are oxide phases, Co3 O4, CuO and PdOx for Co-ZnAl, Cu-ZnAl and Pd-ZnAl catalysts,...

Descripción completa

Detalles Bibliográficos
Autores: Ocsachoque, Marco Antonio, Leguizamón Aparicio, María Silvia del Valle, Casella, Mónica Laura, Lick, Ileana Daniela
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/172377
Acceso en línea:http://hdl.handle.net/11336/172377
Access Level:acceso abierto
Palabra clave:ZINC ALUMINATE
PALLADIUM
COBALT OXIDE
COPPER OXIDE
PROPENE CATALYTIC OXIDATION
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
id AR_0c5e424733e742e6d8fc0bf9e6b4206c
oai_identifier_str oai:ri.conicet.gov.ar:11336/172377
network_acronym_str AR
network_name_str Argentina
repository_id_str
dc.title.none.fl_str_mv Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
title Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
spellingShingle Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
Ocsachoque, Marco Antonio
ZINC ALUMINATE
PALLADIUM
COBALT OXIDE
COPPER OXIDE
PROPENE CATALYTIC OXIDATION
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
title_full Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
title_fullStr Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
title_full_unstemmed Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
title_sort Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation
dc.creator.none.fl_str_mv Ocsachoque, Marco Antonio
Leguizamón Aparicio, María Silvia del Valle
Casella, Mónica Laura
Lick, Ileana Daniela
author Ocsachoque, Marco Antonio
author_facet Ocsachoque, Marco Antonio
Leguizamón Aparicio, María Silvia del Valle
Casella, Mónica Laura
Lick, Ileana Daniela
author_role author
author2 Leguizamón Aparicio, María Silvia del Valle
Casella, Mónica Laura
Lick, Ileana Daniela
author2_role author
author
author
dc.subject.none.fl_str_mv ZINC ALUMINATE
PALLADIUM
COBALT OXIDE
COPPER OXIDE
PROPENE CATALYTIC OXIDATION
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic ZINC ALUMINATE
PALLADIUM
COBALT OXIDE
COPPER OXIDE
PROPENE CATALYTIC OXIDATION
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description Palladium-modified Co-ZnAland Cu-ZnAl materials were used and found active for the catalytic oxidation of propene and propane. According to the results obtained by XRD, TPR and XPS, the zinc aluminate-supported phases are oxide phases, Co3 O4, CuO and PdOx for Co-ZnAl, Cu-ZnAl and Pd-ZnAl catalysts, respectively. These reducible oxide species present good catalytic activity for the oxidation reactions. The addition of palladium to Co-ZnAl or Cu-ZnAl samples promoted the reducibility of the system and, consequently, produced a synergic effect which enhanced the activity for the propene oxidation. The PdCo-ZnAl sample was the most active and exhibited highly dispersed PdOx particles and surface structural defects. In addition, it exhibited good catalytic stability. The H2 pre-treated PdCu-ZnAl, PdCo-ZnAl and Pd-ZnAl samples showed higher activity than the original oxide catalysts, evidencing the important role of the oxidation state of the species, mainly of the palladium species, on the catalytic activity for the propene combustion. The synergic effect between metal transition oxides and PdOx could not be observed for the propane oxidation.
publishDate 2021
dc.date.none.fl_str_mv 2021-08-25
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/172377
Ocsachoque, Marco Antonio; Leguizamón Aparicio, María Silvia del Valle; Casella, Mónica Laura; Lick, Ileana Daniela; Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation; Multidisciplinary Digital Publishing Institute; Materials; 14; 17; 25-8-2021; 4814-4831
1996-1944
CONICET Digital
CONICET
url http://hdl.handle.net/11336/172377
identifier_str_mv Ocsachoque, Marco Antonio; Leguizamón Aparicio, María Silvia del Valle; Casella, Mónica Laura; Lick, Ileana Daniela; Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation; Multidisciplinary Digital Publishing Institute; Materials; 14; 17; 25-8-2021; 4814-4831
1996-1944
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/14/17/4814
info:eu-repo/semantics/altIdentifier/doi/10.3390/ma14174814
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799195896983846912
spelling Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidationOcsachoque, Marco AntonioLeguizamón Aparicio, María Silvia del ValleCasella, Mónica LauraLick, Ileana DanielaZINC ALUMINATEPALLADIUMCOBALT OXIDECOPPER OXIDEPROPENE CATALYTIC OXIDATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Palladium-modified Co-ZnAland Cu-ZnAl materials were used and found active for the catalytic oxidation of propene and propane. According to the results obtained by XRD, TPR and XPS, the zinc aluminate-supported phases are oxide phases, Co3 O4, CuO and PdOx for Co-ZnAl, Cu-ZnAl and Pd-ZnAl catalysts, respectively. These reducible oxide species present good catalytic activity for the oxidation reactions. The addition of palladium to Co-ZnAl or Cu-ZnAl samples promoted the reducibility of the system and, consequently, produced a synergic effect which enhanced the activity for the propene oxidation. The PdCo-ZnAl sample was the most active and exhibited highly dispersed PdOx particles and surface structural defects. In addition, it exhibited good catalytic stability. The H2 pre-treated PdCu-ZnAl, PdCo-ZnAl and Pd-ZnAl samples showed higher activity than the original oxide catalysts, evidencing the important role of the oxidation state of the species, mainly of the palladium species, on the catalytic activity for the propene combustion. The synergic effect between metal transition oxides and PdOx could not be observed for the propane oxidation.Fil: Ocsachoque, Marco Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Leguizamón Aparicio, María Silvia del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaMultidisciplinary Digital Publishing Institute2021-08-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/172377Ocsachoque, Marco Antonio; Leguizamón Aparicio, María Silvia del Valle; Casella, Mónica Laura; Lick, Ileana Daniela; Promoting effect of palladium on ZnAl2O4-supported catalysts based on cobalt or copper oxide on the activity for the total propene oxidation; Multidisciplinary Digital Publishing Institute; Materials; 14; 17; 25-8-2021; 4814-48311996-1944CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1996-1944/14/17/4814info:eu-repo/semantics/altIdentifier/doi/10.3390/ma14174814info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:07:32Zoai:ri.conicet.gov.ar:11336/172377instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:07:33.094CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
score 15,811543

Similares en LA Referencia