“Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions

This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to...

ver descrição completa

Detalhes bibliográficos
Autores: Asteasuain, Mariano, Soares, Matheus, Lenzi, Marcelo K, Cunningham, Michael, Sarmoria, Claudia, Pinto, José Carlos, Brandolin, Adriana
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2007
País:Argentina
Recursos:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/83578
Acesso em linha:http://hdl.handle.net/11336/83578
Access Level:acceso abierto
Palavra-chave:Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
id AR_0c2dae592a37b738eac0fa36c4fcaa1e
oai_identifier_str oai:ri.conicet.gov.ar:11336/83578
network_acronym_str AR
network_name_str Argentina
repository_id_str
spelling “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating FunctionsAsteasuain, MarianoSoares, MatheusLenzi, Marcelo KCunningham, MichaelSarmoria, ClaudiaPinto, José CarlosBrandolin, AdrianaFree RadicalLiving PolymerizationMolecular Weight DistributionModelingProbability Generating Functionshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Soares, Matheus. Universidade Federal do Rio de Janeiro; BrasilFil: Lenzi, Marcelo K. Universidade Federal do Paraná; BrasilFil: Cunningham, Michael. Queens University; CanadáFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pinto, José Carlos. Universidade Federal do Rio de Janeiro; BrasilFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2007-11-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83578Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-6341862-832X1862-8338CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200700026info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200700026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2024-05-08T14:26:32Zoai:ri.conicet.gov.ar:11336/83578instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982024-05-08 14:26:32.325CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
spellingShingle “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
Asteasuain, Mariano
Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
title_short “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_full “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_fullStr “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_full_unstemmed “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
title_sort “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions
dc.creator.none.fl_str_mv Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author Asteasuain, Mariano
author_facet Asteasuain, Mariano
Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author_role author
author2 Soares, Matheus
Lenzi, Marcelo K
Cunningham, Michael
Sarmoria, Claudia
Pinto, José Carlos
Brandolin, Adriana
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
topic Free Radical
Living Polymerization
Molecular Weight Distribution
Modeling
Probability Generating Functions
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
description This is the first of a series of works aiming at developing a tool for designing “living” free radical polymerization processes in tubular reactors, in order to achieve tailor‐made MWDs. A mathematical model of the nitroxide‐mediated controlled free radical polymerization is built and implemented to predict the complete MWD. It is shown that this objective may be achieved accurately and efficiently by means of the probability generating function (pgf) transformation. Comparison with experimental data is good. The potential of the resulting model for optimization activities involving the complete MWD is also shown.
publishDate 2007
dc.date.none.fl_str_mv 2007-11-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83578
Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-634
1862-832X
1862-8338
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83578
identifier_str_mv Asteasuain, Mariano; Soares, Matheus; Lenzi, Marcelo K; Cunningham, Michael; Sarmoria, Claudia; et al.; “Living” Free Radical Polymerization in Tubular Reactors. I. Modeling of the Complete Molecular Weight Distribution Using Probability Generating Functions; Wiley VCH Verlag; Macromolecular Reaction Engineering; 1; 6; 15-11-2007; 622-634
1862-832X
1862-8338
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mren.200700026
info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.200700026
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1799196406781575168
score 15,812429

Registos relacionados