Thermodynamic study of Butylamine + Propanone, + Methyl Isobutyl Ketone (MIK) at (288.15 to 318.15) K temperature range

Experimental determination of density and viscosity of the pure components and [Butylamine (1) + Propanone (2)] and [Butylamine (1) + MIK (2)] binary mixtures at (288.15 to 318.15) K are performed using an Anton Paar SVM 3000/G2 Stabinger Viscometer. The excess molar volume and viscosity deviation a...

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Detalles Bibliográficos
Autores: Campos, Viviana del Valle, Gómez Marigliano, Ana Clelia
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/69520
Acceso en línea:http://hdl.handle.net/11336/69520
Access Level:acceso abierto
Palabra clave:Butylamine
Excess Molar Volume
Thermodynamics
Viscosity Deviation
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
Descripción
Sumario:Experimental determination of density and viscosity of the pure components and [Butylamine (1) + Propanone (2)] and [Butylamine (1) + MIK (2)] binary mixtures at (288.15 to 318.15) K are performed using an Anton Paar SVM 3000/G2 Stabinger Viscometer. The excess molar volume and viscosity deviation are calculated. Correlation equations for the experimental data and calculated functions are obtained. For [Butylamine + Propanone] binary system, the excess molar volume is negative and the viscosity deviation is positive for all temperatures. The values of excess volumes become more negative and the deviations of viscosity more positive with increasing temperature. For [Butylamine + MIK] binary system, the excess molar volume and the viscosity deviation are sigmoid. The excess molar volume is negative and the viscosity deviation is positive until next molar fractions x1 ≈ 0.7.