Sharp fronts in attracting-adatom monolayers

The problem of pattern formation by adsorbates undergoing attractive lateral interactions, is described by a parabolic integrodiffer- ential equation having the scaled inverse temperature ε and the scaled pressure α of the vapor phase as parameters. A coexistence region of high- and low-coverage sta...

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Detalles Bibliográficos
Autores: Wio, H. S., Izus, Gonzalo Gregorio, Deza, R. R.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/8232
Acceso en línea:http://hdl.handle.net/11336/8232
Access Level:acceso abierto
Palabra clave:Non Equilibrium Potential
Adsorption
Pattern Formation
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
Descripción
Sumario:The problem of pattern formation by adsorbates undergoing attractive lateral interactions, is described by a parabolic integrodiffer- ential equation having the scaled inverse temperature ε and the scaled pressure α of the vapor phase as parameters. A coexistence region of high- and low-coverage stable homogeneous states has been reported in the (ε, α) plane. In the small interaction-range limit an effectve dif- fusion coefficient can be defined, which becomes however negative for a coverage range in between the stable homogeneous ones. A novel free-energy-like Lyapunov functional is found here for this prob- lem. When evaluated on the homogeneous states, it leads to a Maxwell- like construction which selects essentially the same value α(ε) as the originally posited zero front-velocity condition. Moreover, its value on static fronts at this particular α(ε) coincides with those of the homo- geneous states. This article is dedicated to Prof. Helmut Brand with occasion of his 60th birthday.