PCB composition in flood material and sediments from the Guadiana River estuary

Two months after moderate river flows, we collected 27 surface sediments from the river-estuarine system and one sediment core from the coastal area. The PCB levels in sediments were lower than 1.1 ng g–1, which is in conformity with the absence of industrial activities in the Guadiana drainage basi...

Descripción completa

Detalles Bibliográficos
Autores: Martins, M, Ferreira, AM, Vales, C
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2005
País:México
Institución:Universidad Autónoma de Baja California Sur
Repositorio:Repositorio Institucional de la UABCS
Idioma:inglés
OAI Identifier:oai:repositorioinstitucional.uabc.mx:20.500.12930/7330
Acceso en línea:https://www.cienciasmarinas.com.mx/index.php/cmarinas/article/view/87
Access Level:acceso abierto
Palabra clave:PCB
congeners
sediments
flood material
Guadiana River
congéneres
sedimentos
material de inundación
Río Guadiana
Descripción
Sumario:Two months after moderate river flows, we collected 27 surface sediments from the river-estuarine system and one sediment core from the coastal area. The PCB levels in sediments were lower than 1.1 ng g–1, which is in conformity with the absence of industrial activities in the Guadiana drainage basin. Material transported by the flood contained higher PCB concentrations (0.8–1.8 ng g–1) than surface sediments (0.1–1.1 ng g–1), indicating the importance of these events in the transport of PCB to this low-contaminated estuarine system. These differences were not related to organic carbon content. Furthermore, this material is enriched in less chlorinated compounds as usually occurs far away from point sources. The diffuse transport influences the CB composition of sediment deposits on the adjacent coast, as revealed by variations in the depth profiles of the tri-/hexa-chlorinated ratio, organic carbon content and Si/Al ratio.