Copper (II) oxide nanowires for p-type conductometric NH3 sensing

Copper (II) oxide (CuO) is a metal oxide suitable for developing solid state gas sensors. Nevertheless, a detailed insight into the chemical-to-electrical transduction mechanisms between gas molecules and this metal oxide is still limited. Here, individual CuO nanowires were evaluated as ammonia (NH...

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Detalhes bibliográficos
Autores: Shao, Feng, Hernández Ramírez, Francisco, Prades García, Juan Daniel, Fàbrega i Claveria, Ma. Carme, Andreu Arbella, Teresa, Morante i Lleonart, Joan Ramon
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/103228
Acesso em linha:https://hdl.handle.net/2445/103228
Access Level:acceso abierto
Palavra-chave:Nanotecnologia
Detectors de gasos
Detectors químics
Nanotechnology
Gas detectors
Chemical detectors
Descrição
Resumo:Copper (II) oxide (CuO) is a metal oxide suitable for developing solid state gas sensors. Nevertheless, a detailed insight into the chemical-to-electrical transduction mechanisms between gas molecules and this metal oxide is still limited. Here, individual CuO nanowires were evaluated as ammonia (NH3) and hydrogen sulphide (H2S) sensors, validating the p-type character of this semiconductor. The working principle behind their performance was qualitatively modeled and it was concluded that adsorbed oxygen at the surface plays a key role necessary to explain the experimental data. Compared to their counterparts of SnO2 nanowires, an appreciable sensitivity enhancement to NH3 for concentrations below 100 ppm was demonstrated.