Development of novel arynes and application to the synthesis of polycyclic aromatic hydrocarbons
Arynes are fascinating intermediates, with a rich reactivity and synthetic versatility. Due to their ability to participate in cycloaddition reactions they constitute privileged platforms for the convergent synthesis of polycyclic aromatic hydrocarbons with potential applications in nanotechnology....
| Autor: | |
|---|---|
| Tipo de recurso: | tesis doctoral |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universidad de Santiago de Compostela (USC) |
| Repositorio: | Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela |
| Idioma: | inglés |
| OAI Identifier: | oai:minerva.usc.gal:10347/24028 |
| Acceso en línea: | http://hdl.handle.net/10347/24028 |
| Access Level: | acceso abierto |
| Palabra clave: | Materias::Investigación::23 Química::2306 Química orgánica::230602 Hidrocarburos aromáticos Materias::Investigación::23 Química::2306 Química orgánica::230610 Compuestos heterocíclicos Materias::Investigación::23 Química::2306 Química orgánica::230603 Derivados del benceno |
| Sumario: | Arynes are fascinating intermediates, with a rich reactivity and synthetic versatility. Due to their ability to participate in cycloaddition reactions they constitute privileged platforms for the convergent synthesis of polycyclic aromatic hydrocarbons with potential applications in nanotechnology. This dissertation collects the authors contributions to the development of novel heteroaryne and polyarynes, and the study of the generation and reactivity of these reactive species. Furthermore, the preparation of particular arenes by using bisarynes is included, as a demonstration of the strength of aryne-based synthetic strategies. |
|---|