Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process

[EN] Nowadays, alternative options to conventional wastewater treatment should be studied due to rising concerns emerged by the presence of pharmaceuticals compounds (PhCs) in the aquatic environment. In this work, a combined system including biological treatment by activated sludge plus adsorption...

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Autores: Ferrer-Polonio, Eva|||0000-0001-6412-3825, Iborra-Clar, María Isabel|||0000-0001-7369-4419, Mendoza Roca, José Antonio, Fernández-Navarro, Julián, Alcaina-Miranda, María Isabel
Tipo de documento: artigo
Data de publicação:2020
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:riunet.upv.es:10251/169901
Acesso em linha:https://riunet.upv.es/handle/10251/169901
Access Level:Acceso aberto
Palavra-chave:Emerging pollutants
Pharmaceutical compounds
Sequencing bath reactor
Activated carbon
INGENIERIA QUIMICA
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spelling Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption processFerrer-Polonio, Eva|||0000-0001-6412-3825Iborra-Clar, María Isabel|||0000-0001-7369-4419Mendoza Roca, José AntonioFernández-Navarro, JuliánAlcaina-Miranda, María IsabelEmerging pollutantsPharmaceutical compoundsSequencing bath reactorActivated carbonINGENIERIA QUIMICA[EN] Nowadays, alternative options to conventional wastewater treatment should be studied due to rising concerns emerged by the presence of pharmaceuticals compounds (PhCs) in the aquatic environment. In this work, a combined system including biological treatment by activated sludge plus adsorption with activated carbon is proposed to remove three selected drugs (acetaminophen (ACT), caffeine (CAF) and ibuprofen (IBU)) in a concentration of 2 mg L-1 of each one. For it three sequencing batch reactors (SBR) were operated. SBR-B treated a synthetic wastewater (SWW) without target drugs and SBR-PhC and SBR-PhC + AC operated with SWW doped with the three drugs, adding into SBR-PhC + AC 1.5 g L-1 of a mesoporous granular activated carbon. Results showed that the hybrid system SBR-activated carbon produced an effluent free of PhCs, which in addition had higher quality than that achieved in a conventional activated sludge treatment in terms of lower COD, turbidity and SMP concentrations. On the other hand, five possible routes of removal for target drugs during the biological treatment were studied. Hydrolysis, oxidation and volatilization pathways were negligible after 6 h of reaction time. Adsorption mute only was significant for ACT, which was adsorbed completely after 5 h of reaction, while only 1.9% of CAF and 5.6% of IBU were adsorbed. IBU was the least biodegradable compound.This work was supported by Spanish grants AICO/2018/292 of the Generalitat Valenciana.ElsevierDepartamento de Ingeniería Química y NuclearEscuela Técnica Superior de Ingeniería IndustrialInstituto Universitario de Seguridad Industrial, Radiofísica y MedioambientalGENERALITAT VALENCIANARepositorio Institucional de la Universitat Politècnica de València Riunet20202020-06-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/169901reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengGeneralitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2018%2F300open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1699012026-06-13T07:49:27Z
dc.title.none.fl_str_mv Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
title Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
spellingShingle Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
Ferrer-Polonio, Eva|||0000-0001-6412-3825
Emerging pollutants
Pharmaceutical compounds
Sequencing bath reactor
Activated carbon
INGENIERIA QUIMICA
title_short Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
title_full Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
title_fullStr Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
title_full_unstemmed Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
title_sort Removal of pharmaceutical compounds commonly-found in wastewater through a hybrid biological and adsorption process
dc.creator.none.fl_str_mv Ferrer-Polonio, Eva|||0000-0001-6412-3825
Iborra-Clar, María Isabel|||0000-0001-7369-4419
Mendoza Roca, José Antonio
Fernández-Navarro, Julián
Alcaina-Miranda, María Isabel
author Ferrer-Polonio, Eva|||0000-0001-6412-3825
author_facet Ferrer-Polonio, Eva|||0000-0001-6412-3825
Iborra-Clar, María Isabel|||0000-0001-7369-4419
Mendoza Roca, José Antonio
Fernández-Navarro, Julián
Alcaina-Miranda, María Isabel
author_role author
author2 Iborra-Clar, María Isabel|||0000-0001-7369-4419
Mendoza Roca, José Antonio
Fernández-Navarro, Julián
Alcaina-Miranda, María Isabel
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Química y Nuclear
Escuela Técnica Superior de Ingeniería Industrial
Instituto Universitario de Seguridad Industrial, Radiofísica y Medioambiental
GENERALITAT VALENCIANA
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Emerging pollutants
Pharmaceutical compounds
Sequencing bath reactor
Activated carbon
INGENIERIA QUIMICA
topic Emerging pollutants
Pharmaceutical compounds
Sequencing bath reactor
Activated carbon
INGENIERIA QUIMICA
description [EN] Nowadays, alternative options to conventional wastewater treatment should be studied due to rising concerns emerged by the presence of pharmaceuticals compounds (PhCs) in the aquatic environment. In this work, a combined system including biological treatment by activated sludge plus adsorption with activated carbon is proposed to remove three selected drugs (acetaminophen (ACT), caffeine (CAF) and ibuprofen (IBU)) in a concentration of 2 mg L-1 of each one. For it three sequencing batch reactors (SBR) were operated. SBR-B treated a synthetic wastewater (SWW) without target drugs and SBR-PhC and SBR-PhC + AC operated with SWW doped with the three drugs, adding into SBR-PhC + AC 1.5 g L-1 of a mesoporous granular activated carbon. Results showed that the hybrid system SBR-activated carbon produced an effluent free of PhCs, which in addition had higher quality than that achieved in a conventional activated sludge treatment in terms of lower COD, turbidity and SMP concentrations. On the other hand, five possible routes of removal for target drugs during the biological treatment were studied. Hydrolysis, oxidation and volatilization pathways were negligible after 6 h of reaction time. Adsorption mute only was significant for ACT, which was adsorbed completely after 5 h of reaction, while only 1.9% of CAF and 5.6% of IBU were adsorbed. IBU was the least biodegradable compound.
publishDate 2020
dc.date.none.fl_str_mv 2020
2020-06-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/169901
url https://riunet.upv.es/handle/10251/169901
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Generalitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2018%2F300
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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