The Impact of Biodegradable Plastics in the Properties of Recycled Polyethylene Terephthalate

[EN] Since biodegradable materials are unwittingly mixed with synthetic materials, this work aimed to study the feasibility of reliably identifying some biopolymers, treated as contaminants, in the recycling process of polyethylene terephthalate (PET). The results showed that the miscibility between...

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Detalhes bibliográficos
Autores: Aldas, Miguel, Bertomeu, David, Pavón-Vargas, Cristina Paola|||0000-0003-2902-0059, Rosa-Ramírez, Harrison de la|||0000-0002-2913-7938, Ferri, J.M|||0000-0002-1269-4973, Samper, María-Dolores|||0000-0002-5102-8412, López-Martínez, Juan|||0000-0001-6904-2282
Formato: artículo
Fecha de publicación:2021
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/232912
Acesso em linha:https://riunet.upv.es/handle/10251/232912
Access Level:acceso abierto
Palavra-chave:Recycling
Polyethylene terephthalate (PET)
Biodegradable materials
Contaminants
Miscibility
12.- Garantizar las pautas de consumo y de producción sostenibles
Descrição
Resumo:[EN] Since biodegradable materials are unwittingly mixed with synthetic materials, this work aimed to study the feasibility of reliably identifying some biopolymers, treated as contaminants, in the recycling process of polyethylene terephthalate (PET). The results showed that the miscibility between PET-PLA and PET-PHB is good. However, PHB is degraded in the recycling of PET due to the high processing temperatures used; meanwhile, PET and TPS are poorly miscible, characteristics also reflected in the microstructure. The contaminants decrease the mechanical properties of the recycled PET. WCA, FTIR, and DSC, do not allow to identify of these contaminants. FESEM resulted in the most successful technique to detect the biodegradable polymers in the PET matrix. No significant degradation of PET under composting conditions was obtained due to the presence of biodegradable polymers, and the effects of the biodegradable contaminants continue to reduce the mechanical performance of the recycled PET after 1 year of storage.