Accelerated ageing of cotton canvas as a model for further consolidation practices

In order to assess the effectiveness of various practices for canvas consolidation, model substrates areneeded. In this work, a method of rapid ageing of cotton canvas is described. The method consists oftreatment of the canvas with a mixture of hydrogen peroxide and sulfuric acid at 40◦C during 72...

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Detalles Bibliográficos
Autores: Nechyporchuk, Oleksandr, Kolman, Krzysztof, Oriola Folch, Marta, Persson, Michael, Holmberg, Krister, 1946-, Bordes, Romain
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/158498
Acceso en línea:https://hdl.handle.net/2445/158498
Access Level:acceso abierto
Palabra clave:Pintura
Conservació i restauració d'obres d'art
Envelliment
Painting
Conservation and restoration of art objects
Aging
Descripción
Sumario:In order to assess the effectiveness of various practices for canvas consolidation, model substrates areneeded. In this work, a method of rapid ageing of cotton canvas is described. The method consists oftreatment of the canvas with a mixture of hydrogen peroxide and sulfuric acid at 40◦C during 72 hoursto mimic to some extent the natural processes of oxidation and acid-catalysed hydrolysis of cellulose.Two protocols for canvas degradation were developed, which reduced the degree of polymerization ofcellulose from ca. 6250 to ca. 1350 and 450. The reduction of the mechanical properties and the increaseof the negative charge were also quantified. These samples were compared with a canvas degraded usinga state-of-the-art method that takes up to 20 days. The results show that the developed method canprovide a rapid procedure for preparing small samples for testing various consolidation strategies byconservators.