Supramolecular polymerization of biphenyl-cyanostilbenes. Triggering circularly polarized luminescence by self-assembly
We report on the synthesis of a series of cyano-luminogens with cyanostilbene fragments, benzamide units, and a nonplanar biphenyl core. Benzamide units drive supramolecular polymerization, forming helical H aggregates via kinetically controlled self-assembly. A sergeants-and-soldiers experiment rev...
| Autores: | , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2025 |
| País: | España |
| Recursos: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/122597 |
| Acesso em linha: | https://hdl.handle.net/20.500.14352/122597 |
| Access Level: | acceso abierto |
| Palavra-chave: | 547 Química orgánica (Química) 2306 Química Orgánica |
| Resumo: | We report on the synthesis of a series of cyano-luminogens with cyanostilbene fragments, benzamide units, and a nonplanar biphenyl core. Benzamide units drive supramolecular polymerization, forming helical H aggregates via kinetically controlled self-assembly. A sergeants-and-soldiers experiment revealed frustrated asymmetry amplification due to the contamination of linear dichroism. The planarization of the central π-conjugated systems enhances aggregation-induced emission affording circularly polarized luminescence-active helical aggregates. |
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