Fluorinated carbohydrates as chemical probes formolecular recognition studies. Current statusand perspectives

This review provides an extensive summary of the effects of carbohydrate fluorination with regard to changes in physical, chemical and biological properties with respect to regular saccharides. The specific structural, conformational, stability, reactivity and interaction features of fluorinated sug...

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Detalles Bibliográficos
Autores: Linclau, Bruno, Ardá, Ana, Reichardt, Niels Christian, Sollogoub, Matthieu, Unione, Luca, Vincent, Stéphane P., Jiménez Barbero, Jesús
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/46950
Acceso en línea:http://hdl.handle.net/10810/46950
Access Level:acceso abierto
Palabra clave:nuclear-magnetic-resonance
udp-galactopyranose mutase
mechanism-based inhibitors
hydrogen-bond acidity
chemoenzymatic synthesis
enantioselective synthesis
organic fluorine
conformational behavior
aromatic interactions
metabolic-inhibitors
Descripción
Sumario:This review provides an extensive summary of the effects of carbohydrate fluorination with regard to changes in physical, chemical and biological properties with respect to regular saccharides. The specific structural, conformational, stability, reactivity and interaction features of fluorinated sugars are described, as well as their applications as probes and in chemical biology.