Biosortion of Cr(VI) from aqueous solutions using chemically modified okra powder

The main objective of this work was to use the okra powder modified with citric acid as biosorbent for the removal of Cr(VI) from aqueous solutions. Samples of Cr(VI) solution were prepared by diluting the 100 ppm solution diluted from the 1000 ppm stock solution prepared with K2Cr2O7. The determina...

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Detalles Bibliográficos
Autores: Silva, Antônio Santos, Conceição, Joelington do C., Ramos, Victor Hugo S., Jesus, Edilson de, Costa, Antônio Wilson M. de C.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:Brasil
Institución:Universidade Federal de Sergipe (UFS)
Repositorio:Repositório Institucional da UFS
Idioma:inglés
OAI Identifier:oai:oai:ri.ufs.br:repo_01:riufs/1430
Acceso en línea:https://ri.ufs.br/handle/riufs/1430
Access Level:acceso abierto
Palabra clave:Quiabo
Biosorvente
Cromo
Equilíbrio químico
Descripción
Sumario:The main objective of this work was to use the okra powder modified with citric acid as biosorbent for the removal of Cr(VI) from aqueous solutions. Samples of Cr(VI) solution were prepared by diluting the 100 ppm solution diluted from the 1000 ppm stock solution prepared with K2Cr2O7. The determination of Cr(VI) was performed spectrophotometrically by the method of complexation with 1,5-diphenylcarbazide, measuring the absorbance at a 540 nm wavelength. The experiments were conducted at 25 ± 1 °C; 2, 5, 7 and 8 initial pH; 10-240 minutes contact time and 0.05 g of adsorbent. The Freundlich and Langmuir models were used to fit the experimental data. The Freundlich model provided R2 =0.9599, indicating adsorption on heterogeneous conditions. Analysis of fluorescence of X-rays, SEM and FTIR were used to prove the okra powder efficiency in the removal of Cr(VI) from aqueous solutions.