Insights into dimethyl sulfoxide decomposition in Li-O 2 battery: Understanding carbon dioxide evolution

DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution...

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Detalles Bibliográficos
Autores: Mozhzhukhina, Nataliia, Marchini, Florencia, Torres, Walter Ramon, Tesio, Alvaro Yamil, Méndez de Leo, Lucila Paula, Williams, Federico José, Calvo, Ernesto Julio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2017
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/65185
Acceso en línea:http://hdl.handle.net/11336/65185
Access Level:acceso abierto
Palabra clave:Lithium
Air
Battery
Dmso
Oxygen
Co2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descripción
Sumario:DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition.